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Poster

Poster

One-pot borylation/Suzuki-Miyaura sp2–sp3 cross-coupling

The Suzuki-Miyaura cross-coupling1,2 is an invaluable C-C bond forming reaction, but it can be limited by theavailability, isolation and stability of the boronate starting materials. This has led to the development of one-potborylation/Suzuki couplings to form sp2–sp2 C‒C bonds,where the intermediate boronates are not isolated(Scheme 1A).3,4, Suzuki/Miyaura couplings are not limited to sp2–sp2 couplings and the one-pot strategy has notpreviously been applied to sp2–sp3 bond formations

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